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Development of an H reduction and moderate oxidation method for 3,5-dimethylpyridine hydrogenation in

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 12,   Pages 1807-1817 doi: 10.1007/s11705-022-2243-2

Abstract: Under the same reduction conditions (300 °C in H<sub>2sub>), the catalytic activity of the non-<i>in-situTherefore, an <i>in-situi> H<sub>2sub> reduction and moderate oxidation method was developed to increasei> H<sub>2sub> reduction and moderate oxidation (oxidized at 100 °C).of the <i>in-situi> H<sub>2sub> reduction and moderate oxidized Ru/C-i2 catalyst, the interactionThe developed <i>in-situi> H<sub>2sub> reduction and moderate oxidation method eliminated the step

Keywords: Ru/C catalyst     <i>in-situi> H<sub>2sub> reduction and moderate oxidation     <i>in-situi> reduction     non-<i>in-situi> reduction     hydrogenation of 3     5-dimethylpyridine    

grown TiN/N-TiO composite for enhanced photocatalytic H evolution activity

Frontiers in Energy 2021, Volume 15, Issue 3,   Pages 721-731 doi: 10.1007/s11708-021-0766-8

Abstract: Titanium nitride (TiN) decorated N-doped titania (N-TiO<sub>2sub>) composite (TiN/N-TiO<sub>2sub>) is fabricated via an <i>in situ i>nitridation using a hydrothermally synthesized TiO<sub>2sub>a hydrogen evolution activity of up to 703 μmol/h under the full spectrum irradiation of Xe-lamp, whichThe results indicate that the superior activity is mainly caused by the <i>in i><i>situ i>formationThe present study provides a fascinating approach to <i>in situi> forming nonmetallic plasmonic material

Keywords: photocatalytic H<sub>2sub> evolution     TiN/N-TiO<sub>2sub> composite     plasmonic effect     <i>in-situi> nitridation    

Evaluation of H<sub>2sub> on the Evolution Mechanism of NO<sub><i>xi>sub> Storage and Reductionover Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub> Catalysts Article

Pan Wang, Jing Yi, Chuan Sun, Peng Luo, Lili Lei

Engineering 2019, Volume 5, Issue 3,   Pages 568-575 doi: 10.1016/j.eng.2019.02.005

Abstract:

In this investigation, Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub> catalysts were preparedby incipient wetness impregnation and experiments were performed to evaluate the influence of H2 onthe evolution mechanism of nitrogen oxides (NO<sub>xsub>) storage and reduction (NSR).and conversion were increased when the time of H<sub>2sub> exposure (i.e., 30 s, 45 s, and 60 s) wasThe results revealed that increasing the content of H<sub>2sub> by an appropriate amount was favorable

Keywords: Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub> catalysts     Physicochemical properties     NO<sub><i>xi>sub> storageand reduction     NO<sub><i>xi>sub> emission     H<sub>2sub> reductant    

NO<sub><i>xi>sub> and H<sub>2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

Frontiers in Energy 2021, Volume 15, Issue 1,   Pages 4-13 doi: 10.1007/s11708-020-0804-y

Abstract: China to control NO emission; thus, it is necessary to understand the formation mechanism of NO and HThis paper focused on the investigation of reductive gases in the formation of NO and H S in the reductiveZD into GE was found to increase not only the coal conversion but also the concentrations of CO and HS as NO reduction accelerated.Based on accumulated experimental data, one interesting finding was that NO and H S from blended coal

Keywords: blended coal combustion     NO<sub><i>x i>sub>formation     H<sub>2sub>S formation     air staged combustion    

encapsulating M(Co, Fe)-Ni alloy for electrochemical production of syngas with potential-independent CO/H

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 4,   Pages 498-510 doi: 10.1007/s11705-021-2082-6

Abstract: The electrochemical conversion of CO<sub>2sub>-H<sub>2sub>O into CO-H<sub>2sub> using renewableLow-cost electrocatalysts to produce tunable syngas with a potential-independent CO/H<sub>2sub> ratioConsequently, syngas with a wide range of CO/H<sub>2sub> ratios, from 0.5:1 to 3.4:1, can be producedMore importantly, stable CO/H<sub>2sub> ratios of 2:1 and 1.5:1, corresponding to the ratio to producesub>2sub> ratio from electrochemical CO<sub>2sub> reduction.

Keywords: electrochemical reduction of CO<sub>2sub>     syngas     <i>Ni>-doped carbon nanotubes     encapsulated alloynanoparticles     CO/H<sub>2sub> ratio    

><i>In situi> growth of phosphorized ZIF-67-derived amorphous CoP/Cu<sub>2sub>O@CF electrocatalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1430-1439 doi: 10.1007/s11705-023-2320-1

Abstract: Herein, we report an <i>in situi> phosphorization of zeolitic imidazole frameworks (ZIF-67) to generateThe intermediate product was phosphorized to obtain final electrocatalyst (CoP/Cu<sub>2sub>O@CF) withdi>-band center of CoP downshifted after bonding with ZIF-67 and the Gibbs free energy (Δ<i>Gi><sub>H*sub>) changed from –0.18 to –0.11 eV, confirming both decrease in overpotential and excellent HERThis work illustrates the efficient HER activity of CoP/Cu<sub>2sub>O@CF catalyst, which will act as

Keywords: CoP/Cu<sub>2sub>O@CF     electrocatalyst     phosphorization     HER     DFT    

Graphene-like -BN supported polyhedral NiS/NiS nanocrystals with excellent photocatalytic performance for removing rhodamine B and Cr(VI)

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1537-1549 doi: 10.1007/s11705-021-2094-2

Abstract: In this work, <i>hi>-BN/NiS<sub>2sub>/NiS composites were prepared via a simple solvothermal methodThe 7 wt-% <i>hi>-BN/NiS<sub>2sub>/NiS composites were characterized via a larger specific surfaceHowever, the removal rate of RhB by the 7 wt-% <i>hi>-BN/NiS<sub>2sub>/NiS photocatalyst reachedThis is due to the double Z-scheme heterojunction formed between NiS<sub>2sub>/NiS and <i>hi>-BN,hi>-BN promoted transportation of photoinduced charges on the surface of the <i>hi>-BN/NiS<sub>2<

Keywords: graphene-like <i>hi>-BN     <i>hi>-BN/NiS<sub>2sub>/NiS composites     photocatalysis     Cr(VI) reduction    

<i>Ni>-Positive ion activated rapid addition and mitochondrial targeting ratiometric fluorescent probesfor <i>in vivoi> cell H<sub>2sub>S imaging

Yan Shi, Fangjun Huo, Yongkang Yue, Caixia Yin

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 1,   Pages 64-71 doi: 10.1007/s11705-021-2048-8

Abstract: work, we combine these two groups organically to construct a rapid response site (within 30 s) for HS, and at the same time, a ratiometric fluorescence response is presented throughout the process of HAs such, the lower detection limit can reach 55.7 nmol/L for H S.shows that this probe can be used for the mitochondrial targeted detection of endogenous and exogenous HFinally, this probe application was verified by imaging H S in nude mice.

Keywords: heterocyclic compound     hydrogen sulfide     ratiometric     mitochondrial targeted    

CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction mechanistic study

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 5, doi: 10.1007/s11783-022-1539-2

Abstract:

• CeO<sub>2sub> doping significantly improved low-temperature NH<sub>3sub>-SCR activity on FeTiO<sub><i>xi>sub>.

Keywords: NH<sub>3sub>-SCR     CeO<sub>2sub> doping     Low-temperature NO<sub><i>xi>sub> removal     Improved redoxproperty     <i>In situi> XAFS analysis    

Reduction kinetics of SrFeO/CaO∙MnO nanocomposite as effective oxygen carrier for chemical looping partialoxidation of methane

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 12,   Pages 1726-1734 doi: 10.1007/s11705-022-2188-5

Abstract: In this work, the kinetics of SrFeO<sub>3−<ii>sub>–CaO∙MnO nanocomposite reduction by methane wasDuring the methane reduction, combustion occurs before the partial oxidation and there exists a transitionwith <i>ni> = 3 (A3 model) with an activation energy of 59.8 kJ∙mol‒1.The partial oxidation is half order with respect to methane pressure.The proposed rate law could well predict the reduction kinetics; thus, it may be used to design and/or

Keywords: chemical looping reforming     SrFeO<sub>3−<ii>sub>/CaO·MnO nanocomposite     reduction kinetics     Avrami–Erofeyev    

Effects of Pd doping on N

Mingxin Dong, Jun Wang, Jinxin Zhu, Jianqiang Wang, Wulin Wang, Meiqing Shen

Frontiers of Environmental Science & Engineering 2017, Volume 11, Issue 6, doi: 10.1007/s11783-017-0976-9

Abstract: These catalysts were first evaluated in NSR activity tests using H /CO as reductants and then carefullycharacterized by BET, CO chemisorption, CO-DRIFTs and H -TPR techniques.Compared with Pt/BaO/Al O , (Pt/BaO/Al O +Pd/Al O ) produced less N O and more NH during NO storage and reductionO +Pd/Al O ) played an important role in NO reduction to NH , and the formed NH could reduce NO toBaO/Al O , which inhibits the NO dissociation and thus drives the selectivity to N O in NO reduction.

Keywords: NO<sub><i>xi>sub> storage reduction     Pt/BaO/Al<sub>2sub>O<sub>3sub>     Pd doping     N<sub>2sub>O formation    

Anodic oxidation of azo dye C.I. Acid Red 73 by the yttrium-doped Ti/SnO

Li XU, Zhi GUO, Lishun DU

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 3,   Pages 338-346 doi: 10.1007/s11705-013-1335-4

Abstract: This work was conducted to study the ability of anodic oxidation of azo dye C.I.

Keywords: SnO<sub>2sub>-Sb     yttrium doping     anodic oxidation     azo dyes    

On the monolayer dispersion behavior of Co<sub>3sub>O<sub>4sub> on HZSM-5 support: designing applicablecatalysts for selective catalytic reduction of nitrogen oxides by ammonia

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 11,   Pages 1741-1754 doi: 10.1007/s11705-023-2332-x

Abstract: have been prepared for selective catalytic reduction of nitrogen oxides by ammonia.It has been revealed that the quantities of surface active oxygen (O<sub>2sub>) and acidsites are crucial for the reaction, which can adsorb and activate NO<sub><i>xi>sub> and NH<sub>3generate the two kinds of active sites, hence promoting the performance of ammonia selective catalytic reductioncapacity, possesses the most abundant active O<sub>2sub> species and acidic sites, thereby

Keywords: Co<sub>3sub>O<sub>4sub>/ZSM-5     NO<sub><i>xi>sub>-SCR by NH<sub>3sub>     monolayer dispersionthreshold effect     surface acid sites     surface active O<sub>2sub> anions    

Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective catalytic reduction

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4,   Pages 594-602 doi: 10.1007/s11705-017-1668-5

Abstract: deposition method was used to fabricate Mn-based catalysts on a UiO-66 carrier for the selective catalytic reductionThe 8.5 wt-% MnO catalyst maintained excellent activity during a 24-h stability test and exhibited good

Keywords: metal-organic framework     selective catalytic reduction     manganese oxides     deNO<sub><i>xi>sub>     SO<sub>2sub> resistance    

Removal of P<sub>4sub>, PH<sub>3sub> and H<sub>2sub>S from Yellow Phosphoric Tail Gas by a CatalyticOxidation Process

Ning Ping,Hans-Jörg Bart,Wang Xueqian,Ma Liping,Chen Liang

Strategic Study of CAE 2005, Volume 7, Issue 6,   Pages 27-35

Abstract: In this study, catalytic oxidation of phosphorus and hydrogen sulfide in yellow phosphorus tail gas wasinvestigated with activated carbon and a home-made catalyst KU2.Both KU2 and activated carbon proved to be effective catalysts in the catalytic oxidation process (COP) for H<sub>2sub>S and PH<sub>3sub> removal.

Keywords: catalyst     catalytic oxidation     H<sub>2sub>S     P<sub>4sub>     PH<sub>3sub>     fixed bed    

Title Author Date Type Operation

Development of an H reduction and moderate oxidation method for 3,5-dimethylpyridine hydrogenation in

Journal Article

grown TiN/N-TiO composite for enhanced photocatalytic H evolution activity

Journal Article

Evaluation of H<sub>2sub> on the Evolution Mechanism of NO<sub><i>xi>sub> Storage and Reductionover Pt–Ba–Ce/γ-Al<sub>2sub>O<sub>3sub> Catalysts

Pan Wang, Jing Yi, Chuan Sun, Peng Luo, Lili Lei

Journal Article

NO<sub><i>xi>sub> and H<sub>2sub>S formation in the reductive zone of air-staged combustion of

Jinzhi CAI, Dan LI, Denggao CHEN, Zhenshan LI

Journal Article

encapsulating M(Co, Fe)-Ni alloy for electrochemical production of syngas with potential-independent CO/H

Journal Article

><i>In situi> growth of phosphorized ZIF-67-derived amorphous CoP/Cu<sub>2sub>O@CF electrocatalyst

Journal Article

Graphene-like -BN supported polyhedral NiS/NiS nanocrystals with excellent photocatalytic performance for removing rhodamine B and Cr(VI)

Journal Article

<i>Ni>-Positive ion activated rapid addition and mitochondrial targeting ratiometric fluorescent probesfor <i>in vivoi> cell H<sub>2sub>S imaging

Yan Shi, Fangjun Huo, Yongkang Yue, Caixia Yin

Journal Article

CeO doping boosted low-temperature NH-SCR activity of FeTiO catalyst: A microstructure analysis and reaction mechanistic study

Journal Article

Reduction kinetics of SrFeO/CaO∙MnO nanocomposite as effective oxygen carrier for chemical looping partialoxidation of methane

Journal Article

Effects of Pd doping on N

Mingxin Dong, Jun Wang, Jinxin Zhu, Jianqiang Wang, Wulin Wang, Meiqing Shen

Journal Article

Anodic oxidation of azo dye C.I. Acid Red 73 by the yttrium-doped Ti/SnO

Li XU, Zhi GUO, Lishun DU

Journal Article

On the monolayer dispersion behavior of Co<sub>3sub>O<sub>4sub> on HZSM-5 support: designing applicablecatalysts for selective catalytic reduction of nitrogen oxides by ammonia

Journal Article

Metal-organic framework loaded manganese oxides as efficient catalysts for low-temperature selective catalytic reduction

Minhua Zhang, Baojuan Huang, Haoxi Jiang, Yifei Chen

Journal Article

Removal of P<sub>4sub>, PH<sub>3sub> and H<sub>2sub>S from Yellow Phosphoric Tail Gas by a CatalyticOxidation Process

Ning Ping,Hans-Jörg Bart,Wang Xueqian,Ma Liping,Chen Liang

Journal Article